| 1 | » Sébastien Buemi (CH)
» Brendon Hartley (NZ)
» Ryo Hirakawa (J) | Toyota GR010 HYBRID | Toyota Gazoo Racing | 47 | 1:37,692 | | 213,475 |
| 2 | » Paul di Resta (GB)
» Jean-Éric Vergne (F)
» Mikkel Jensen (DK) | Peugeot 9X8 | Peugeot TotalEnergies | 37 | 1:37,775 | 0:00,083 | 213,293 |
| 3 | » Romain Dumas (F)
» Olivier Pla (F)
» Pipo Derani (BR) | Glickenhaus 007 LMH | Glickenhaus Racing | 48 | 1:37,961 | 0:00,269 | 212,888 |
| 4 | » Loic Duval (F)
» James Rossiter (GB)
» Gustavo Menezes (USA) | Peugeot 9X8 | Peugeot TotalEnergies | 38 | 1:38,061 | 0:00,369 | 212,671 |
| 5 | » Nicolas Lapierre (F)
» André Negrão (BR)
» Matthieu Vaxivière (F) | Alpine A480 | Alpine Elf Endurance Team | 48 | 1:38,082 | 0:00,390 | 212,626 |
| 6 | » Kamui Kobayashi (J)
» José Maria López (RA)
» Mike Conway (GB) | Toyota GR010 HYBRID | Toyota Gazoo Racing | 46 | 1:38,116 | 0:00,424 | 212,552 |
| 7 | » Filipe Albuquerque (P)
» Philip Hanson (GB)
» Will Owen (USA) | ORECA 07 | United Autosports USA | 45 | 1:38,917 | 0:01,225 | 210,831 |
| 8 | » François Perrodo (F)
» Nicklas Nielsen (DK)
» Alessio Rovera (I) | ORECA 07 | AF Corse | 49 | 1:39,172 | 0:01,480 | 210,289 |
| 9 | » René Rast (D)
» Robin Frijns (NL)
» Sean Gelael (RI) | ORECA 07 | WRT | 46 | 1:39,186 | 0:01,494 | 210,259 |
| 10 | » Miroslav Konopka (SK)
» Mathias Beche (CH)
» Tijmen van der Helm (NL) | ORECA 07 | ARC Bratislava | 46 | 1:39,253 | 0:01,561 | 210,117 |
| 11 | » Oliver Jarvis (GB)
» Alex Lynn (GB)
» Josh Pierson (USA) | ORECA 07 | United Autosports USA | 44 | 1:39,315 | 0:01,623 | 209,986 |
| 12 | » Edward Jones (GB)
» Jonathan Aberdein (ZA)
» Oliver Rasmussen (DK) | ORECA 07 | JOTA | 41 | 1:39,331 | 0:01,639 | 209,952 |
| 13 | » Norman Nato (F)
» Ferdinand Habsburg (A)
» Rui Andrade (P) | ORECA 07 | Realteam by WRT | 48 | 1:39,443 | 0:01,751 | 209,716 |
| 14 | » António Félix da Costa (P)
» Will Stevens (GB)
» Roberto Gonzalez (MEX) | ORECA 07 | JOTA | 43 | 1:39,801 | 0:02,109 | 208,963 |
| 15 | » Robert Kubica (PL)
» Louis Delétraz (CH)
» Lorenzo Colombo (I) | ORECA 07 | Prema ORLEN Team | 41 | 1:39,903 | 0:02,211 | 208,750 |
| 16 | » Sébastien Bourdais (F)
» Nico Müller (CH)
» Ryan Cullen (IRL) | ORECA 07 | Vector Sport | 36 | 1:39,988 | 0:02,296 | 208,573 |
| 17 | » Rene Binder (A)
» James Allen (AUS)
» Steven Thomas (USA) | ORECA 07 | Algarve Pro Racing | 39 | 1:40,183 | 0:02,491 | 208,167 |
| 18 | » Paul-Loup Chatin (F)
» Charles Milesi (F)
» Lilou Wadoux (F) | ORECA 07 | Richard Mille Racing Team | 37 | 1:40,437 | 0:02,745 | 207,640 |
| 19 | » Esteban Gutiérrez (MEX)
» Alex Brundle (GB)
» Jakub Smiechowski (PL) | ORECA 07 | Inter Europol Competition | 48 | 1:40,520 | 0:02,828 | 207,469 |
| 20 | » Matthieu Lahaye (F)
» Jean-Baptiste Lahaye (F)
» François Heriau (F) | ORECA 07 | Ultimate | 45 | 1:41,242 | 0:03,550 | 205,989 |
| 21 | » Gianmaria Bruni (I)
» Frédéric Makowiecki (F) | Porsche 911 RSR-19 | Porsche GT Team | 39 | 1:46,245 | 0:08,553 | 196,289 |
| 22 | » Miguel Molina (E)
» Antonio Fuoco (I) | Ferrari 488 GTE Evo | AF Corse | 43 | 1:46,714 | 0:09,022 | 195,427 |
| 23 | » Alessandro Pier Guidi (I)
» James Calado (GB) | Ferrari 488 GTE Evo | AF Corse | 44 | 1:46,816 | 0:09,124 | 195,240 |
| 24 | » Michael Christensen (DK)
» Kévin Estre (F) | Porsche 911 RSR-19 | Porsche GT Team | 43 | 1:47,063 | 0:09,371 | 194,789 |
| 25 | » Tommy Milner (USA)
» Nick Tandy (GB) | Chevrolet Corvette C8.R | Corvette Racing | 35 | 1:47,255 | 0:09,563 | 194,441 |
| 26 | » Nicolas Leutwiler (CH)
» Matteo Cairoli (I)
» Mikkel Overgaard Pedersen (DK) | Porsche 911 RSR-19 | Team Project 1 | 43 | 1:47,738 | 0:10,046 | 193,569 |
| 27 | » Toni Vilander (FIN)
» Christoph Ulrich (CH)
» Simon Mann (USA) | Ferrari 488 GTE Evo | AF Corse | 45 | 1:47,757 | 0:10,065 | 193,535 |
| 28 | » Francesco Castellacci (I)
» Nick Cassidy (NZ)
» Thomas Flohr (CH) | Ferrari 488 GTE Evo | AF Corse | 42 | 1:47,777 | 0:10,085 | 193,499 |
| 29 | » Mike Wainwright (GB)
» Ben Barker (GB)
» Riccardo Pera (I) | Porsche 911 RSR-19 | GR Racing | 41 | 1:47,817 | 0:10,125 | 193,427 |
| 30 | » Marco Sørensen (DK)
» Ben Keating (USA)
» Henrique Chaves Jr. (P) | Aston Martin Vantage AMR | TF Sport | 45 | 1:47,883 | 0:10,191 | 193,309 |
| 31 | » Christian Ried (D)
» Harry Tincknell (GB)
» Seb Priaulx (GB) | Porsche 911 RSR-19 | Dempsey-Proton Racing | 40 | 1:47,951 | 0:10,259 | 193,187 |
| 32 | » Giancarlo Fisichella (I)
» Matteo Cressoni (I)
» Claudio Schiavoni (I) | Ferrari 488 GTE Evo | Iron Lynx | 41 | 1:47,985 | 0:10,293 | 193,126 |
| 33 | » Ollie Millroy (GB)
» Brendan Iribe (USA)
» Ben Barnicoat (GB) | Porsche 911 RSR-19 | Team Project 1 | 44 | 1:48,024 | 0:10,332 | 193,057 |
| 34 | » Nicki Thiim (DK)
» Paul Dalla Lana (CDN)
» David Pittard (GB) | Aston Martin Vantage AMR | Northwest AMR | 39 | 1:48,205 | 0:10,513 | 192,734 |
| 35 | » Rahel Frey (CH)
» Michelle Gatting (DK)
» Sarah Bovy (B) | Ferrari 488 GTE Evo | Iron Dames | 37 | 1:48,216 | 0:10,524 | 192,714 |
| 36 | » Pierre Ragues (F)
» Gabriel Aubry (F)
» Franck Dezoteux (F) | Ferrari 488 GTE Evo | Spirit of Race | 30 | 1:48,385 | 0:10,693 | 192,414 |
| 37 | » Jan Heylen (B)
» Fred Poordad (USA)
» Patrick Lindsey (USA) | Porsche 911 RSR-19 | Dempsey-Proton Racing | 40 | 1:48,395 | 0:10,703 | 192,396 |
| 38 | » Tomonobu Fujii (J)
» Satoshi Hoshino (J)
» Charlie Fagg (GB) | Aston Martin Vantage AMR | D'Station Racing | 44 | 1:48,456 | 0:10,764 | 192,288 |
